Second-generation circumbinary discs around evolved binary stars, such as post-Asymptotic Giant Branch (post-AGB) binaries, provide insights into poorly understood mechanisms of dust processing and disc evolution across diverse stellar environments. We present a multi-wavelength polarimetric survey of five evolved binary systems — ARPup, HR4049, HR4226, UMon, and V709 Car — using the Very Large Telescope SPHERE/ZIMPOL instrument. Post-AGB discs show significant polarimetric brightness at optical and near-IR wavelengths, often exceeding 1% of the system’s total intensity. We also measured a maximum fractional polarisation of the scattered light for ARPup of ∼0.7 in the V-band and ∼0.55 in the I-band. To investigate wavelength-dependent polarisation, we combine the SPHERE/ZIMPOL dataset with results from previous SPHERE/IRDIS studies. This analysis reveals that post-AGB discs exhibit a grey to blue polarimetric colour in the optical and near-IR. Along with high fractional polarisation of the scattered light and polarised intensity distribution, these findings are consistent with a surface dust composition dominated by porous aggregates, reinforcing independent observational evidence for such grains in post-AGB circumbinary discs. We also find evidence of diverse disc geometries within the post-AGB sample, including arcs, asymmetries and significant variations in disc size across optical and near-IR wavelengths for some systems (UMon, V709 Car). Combining our findings with existing multi-technique studies, we question the classification of two systems in our sample, HR 4226 and V709 Car, which were originally identified as post-AGB binaries based on their near-IR excess. On comparing post-AGB discs to circumstellar environments around AGB stars and YSOs, we found that post-AGB systems exhibit a higher degree of polarisation than single AGB stars and are comparable to the brightest protoplanetary discs around YSOs. Overall, our results reinforce the importance of polarimetric observations in probing dust properties and complex circumbinary structures. We also highlight the importance of combining multi-wavelength and multi-technique observations with advanced radiative-transfer modelling to differentiate between the various evolutionary pathways of circumbinary discs.