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X-Ray Microscopy Of Multiphase Polymeric Materials

Published online by Cambridge University Press:  15 February 2011

H. Ade ,
A. P. Smith ,
G. R. Zhuang ,
B. Wood ,
I. Plotzker ,
E. Rightor ,
D.-J. Liu ,
S.-C. Lui  and
C. Sloop
H. Ade
Affiliation:
Dept. of Physics, North Carolina State University, Raleigh, NC 27695–8202
A. P. Smith
Affiliation:
Dept. of Physics, North Carolina State University, Raleigh, NC 27695–8202
G. R. Zhuang
Affiliation:
Dept. of Physics, North Carolina State University, Raleigh, NC 27695–8202
B. Wood
Affiliation:
Experimental Station, DuPont, Wilmington, DE 19880–0323
I. Plotzker
Affiliation:
Experimental Station, DuPont, Wilmington, DE 19880–0323
E. Rightor
Affiliation:
Texas Polymer Center, B-1470, Dow Chemical, Freeport, TX 77541
D.-J. Liu
Affiliation:
AlliedSignal Technology, 50 E. Algonquin Rd., Des Plaines, IL 60017–5016
S.-C. Lui
Affiliation:
AlliedSignal Technology, 50 E. Algonquin Rd., Des Plaines, IL 60017–5016
C. Sloop
Affiliation:
IBM Corp., Research Triangle Park, NC
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Abstract

We have utilized the scanning transmission x-ray microscope at Brookhaven National Laboratory to acquire high energy resolution spectra of various polymers and to investigate the bulk characteristics of multiphasic polymeric materials with chemical sensitivity at a spatial resolution of about 50 nm. We present studies ranging from phase separated liquid crystalline polyesters and polyurethanes to various polymer blends. Improvements in the NEXAFS imaging and spectral acquisition protocol in the recent past provide much improved spectral fidelity and include in situ energy calibration with CO2.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 437: Symposium DD – Applications of Synchrotron Radiation to III , 1996 , 99
Copyright
Copyright © Materials Research Society 1996

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References

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