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Tin-Based Hybrid Materials as Precursors of Mesoporous Tin Oxide

Published online by Cambridge University Press:  01 February 2011

Bernard Jousseaume ,
Hocine Riague ,
Thierry Toupance  and
Mohamed Lahcini
Bernard Jousseaume
Affiliation:
Laboratoire de Chimie Organique et Organométallique, UMR 5802, Université Bordeaux I, Talence, France;
Hocine Riague
Affiliation:
Laboratoire de Chimie Organique et Organométallique, UMR 5802, Université Bordeaux I, Talence, France;
Thierry Toupance
Affiliation:
Laboratoire de Chimie Organique et Organométallique, UMR 5802, Université Bordeaux I, Talence, France;
Mohamed Lahcini
Affiliation:
Département de Chimie, Université Cadi Ayyad, Marrakech, Morocco.
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Abstract

Alkylene-, arylene- or benzylene-bridged ditin hexachlorides were obtained in high yields from the reaction of the corresponding hexacyclohexylated compounds with tin tetrachloride. These intermediates were successfully transformed into the corresponding alkynides, which gave gels of hybrid materials on hydrolysis. This is the first example of a gel formation from a organometal with the metal fully substituted with covalently-linked organic groups. Subsequent thermal treatment led to mesoporous tin oxide with high surface area and narrow pore size distribution.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 726: Symposium Q – Hybrid Organic-Inorganic Materials , 2002 , Q6.6
Copyright
Copyright © Materials Research Society 2002

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