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Synthetic and Structural Studies Bismuth/Copper Alkoxides

Published online by Cambridge University Press:  28 February 2011

William J. Evans  and
John H. Hain Jr.
William J. Evans
Affiliation:
Department of Chemistry, University of California-Irvine, Irvine, California 92717
John H. Hain Jr.
Affiliation:
Department of Chemistry, University of California-Irvine, Irvine, California 92717
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Abstract

The reaction of Bi[OC(CH3)3]3 with [Cu(μ-O2CCH3)2]2 has been investigated as a possible route to mixed-metal materials containing bismuth and copper. The product distribution obtained from this reaction depends not only upon the stoichiometry, but also upon the method of product isolation. Products containing bismuth and copper are obtainable as well as an unusual, soluble hexametallic copper(II) alkoxide acetate complex, Cu6[OC(CH3)3]6(O2CCH3)6. The mixed-metal products were examined by differential scanning calorimetry, and thermolyzed and hydrolyzed samples of these products were compared by scanning electron microscopy.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 180: Symposium A – Better Ceramics Through Chemistry IV , 1990 , 39
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Bednorz, J. G., Muller, K. A., and Takashige, M., Science (Washington, DC) 236, 73 (1987).Google Scholar
2. Maeda, H., Tanaka, Y., Fukutomi, M., and Asano, T., Jpn. J. Appl. Phys. 27, L209 (1988).Google Scholar
3. Sheng, Z. Z. and Hermann, A. M., Nature (London) 332, 138 (1988).Google Scholar
4. Better Ceramics Through Chemistry II, edited by Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mat. Res. Soc. Symp. Proc. 73, and references therein.Google Scholar
5. Horowitz, H. S., McLain, S. J., Sleight, A. W., Druliner, J. D., Gai, P. L., VanKavelaar, M. J., Wagner, J. L., Biggs, B. D., and Poon, S. J., Science 243, 66 (1989).Google Scholar
6. Hubert-Pfalzgraf, L. G., New J. Chem. 11, 663 (1987) and references therein.Google Scholar
7. Livage, J., Henry, M., and Sanchez, C., Prog. Solid St. Chem. 18, 259 (1988).Google Scholar
8. Evans, W. J., Hain, J. H. Jr., and Ziller, J. W., J. Chem. Soc., Chem. Commun. 1628 (1989).Google Scholar
9. Goel, S. C., Kramer, K. S., Gibbons, P. C., and Buhro, W. E., Inorg. Chem. 28, 3619 (1989) and references therein.Google Scholar