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Synthesis of New Multiple Layered Dion-Jacobson Perovskites

Published online by Cambridge University Press:  09 May 2014

Léa Gustin ,
Jérôme Lefebvre ,
Clare Davis-Wheeler ,
Amy K. Pressley  and
John B. Wiley
Léa Gustin*
Affiliation:
Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148
Jérôme Lefebvre
Affiliation:
Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148
Clare Davis-Wheeler
Affiliation:
Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148
Amy K. Pressley
Affiliation:
Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148
John B. Wiley
Affiliation:
Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148
*
*Email: lgustin@uno.edu
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Abstract

New multiple layered perovskites with general formula RbLaNaxNb2+xO7+3x, x = 1 and 2, were synthesized via a ceramic method. While the triple layered compound could be obtained by simple direct reaction, the quadruple layered one was synthesized using a two-step solid state approach. The compounds were characterized by X-ray powder diffraction; the newly obtained compounds appear to be isostructural with the previously reported RbCa2Nb3O10 and RbCa2NaNb4O13 for RbLaNaNb3O10 and RbLaNa2Nb4O13, respectively. Preliminary results show that the new compounds can undergo ion exchange reactions involving alkali metals and transition metal chlorides.

Keywords

chemical synthesisoxidex-ray diffraction (XRD)

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Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1655: Symposium OO – Solid-State Chemistry of Inorganic Materials , 2014 , mrsf13-1655-oo06-05
Copyright
Copyright © Materials Research Society 2014 

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References

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