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Surface Chemistry of Energetic Materials at High Temperature

Published online by Cambridge University Press:  15 February 2011

Thomas B. Brill
Thomas B. Brill*
Affiliation:
University of Delaware, Department of Chemistry, Newark, DE 19716
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Abstract

The chemistry at the surface of a burning propellant plays a major role in the burnrate, the stability of the flame, and the potential for a run-away hazardous event. Chemical details can be determined experimentally by simulating the burning surface with a thin film of material heated rapidly to the surface temperature. T-Jump/FTIR spectroscopy is designed to create these conditions. The dominant, initial, heat-producing reactions in the surface zone of NH4ClO4, NH4NO3, NH4[N(NO2)2], HMX, RDX, and DNNC are elucidated at high temperatures representative of the burning surface.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 296: Symposium Y – Structure and Properties of Energetic Materials , 1992 , 269
Copyright
Copyright © Materials Research Society 1993

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References

1. Rice, O. K. and Ginell, R., J. Phys. Chem., 54, 885 (1950).Google Scholar
2. Guirao, C. and Williams, F. A., AIAA J., 9, 1345 (1971).Google Scholar
3. Mitani, T. and Williams, F. A., Proc. 21st Symp. (Int.) Combustion, 1986, p. 1965.Google Scholar
4. Ben-Reuven, M. and Caveny, L H., AIAA J., 19, 1276 (1979).Google Scholar
5. Cohen, N. S., Lo, G. A. and Crowley, J. C., AIAA J., 23, 276 (1985).Google Scholar
6. Kubota, N. and Sakamoto, S., Prop. Explos. Pyrotech., 14, 6 (1989).CrossRefGoogle Scholar
7. Chi, M., Gleeson, B., Hill, J. and Wilier, R., US Patent 5071495, Dec. 1991.Google Scholar
8. Stoner, C. E. Jr. and Brill, T. B., Combust. Flame, 83, 302 (1991).Google Scholar
9. Brill, T. B., Brush, P. J., James, K. J., Shepherd, J. E. and Pfeiffer, K. J., Appl. Spectrosc., 46, 900 (1992).Google Scholar
10. Brill, T. B., Prog. Energy Combust. Sci., 18, 91 (1992).Google Scholar
11. Timken, M. D., Chen, J. K. and Brill, T. B., Appl. Spectrosc., 44, 701 (1990).Google Scholar
12. Chen, J. K. and Brill, T. B., Combust. Flame, 85, 479 (1991).Google Scholar
13. Chen, J. K. and Brill, T. B., Combust. Flame, 87, 157 (1991).Google Scholar
14. Chen, J. K. and Brill, T. B., Combust. Flame, 87, 217 (1991).Google Scholar
15. Brill, T. B., Patil, D. G., Duterque, J. P. and Lengelle, G., Combust. Flame, sumbitted.Google Scholar
16. Brill, T. B., Brush, P. J. and Patil, D. G., Combust. Flame, submitted.Google Scholar
17. Ermolin, N. E., Korobeinichev, O. P., Tereshenko, A. G. and Fomin, V. M., Comb. Explos. Shock Waves, 18, 180 (1992).Google Scholar
18. Korobeinichev, O. P. and Tereshenko, A. G., in Tenth Mat. Res. Symp. Charact. High Temp. Vapors and Gases, NBS publ. 561, Gaithersburg, MD, 1978, p. 479.Google Scholar
19. Hackman, E. E., Hesser, H. H. and Beachell, H. C., J. Phys. Chem., 76, 3545 (1972).Google Scholar
20. Brill, T. B., Brush, P. J. and Patil, D. G., Combust. Flame, in press.Google Scholar
21. Swett, M., NWC, personal communication (1992).Google Scholar
22. Whittaker, A. G. and Barham, D. C., J. Phys. Chem., 68, 196 (1964).CrossRefGoogle Scholar
23. Federoff, B. T., Encyclopedia of Explosives and Related Items, Vol. I, Picatinny Arsenal, Dover, NJ, 1960, A3111.Google Scholar
24. Kaiser, R., Angew. Chem., 48, 149 (1935).Google Scholar
25. Rosser, W. A. and Wise, H., J. Chem. Phys., 25, 1078 (1956).Google Scholar
26. Bedford, G. and Thomas, J. H., J. Chem. Soc. Farad. Trans. I, 2163 (1972).Google Scholar
27. Fetherolf, B. L. and Litzinger, T. A., Penn State Univ., personal communication (1992).Google Scholar
28. Brill, T. B. and Brush, P. J., Phil. Trans. Royal Soc. (Lond.) A, 339, 377 (1992).Google Scholar
29. Brill, T. B., Brush, P. J., Patil, D. G. and Chen, J. K., Proc. 28th SYmp. (Int.) Combustion. Sydney, Australia, July, 1992.Google Scholar
30. Cosgrove, J. D. and Owen, A. J., Combust. Flame, 22, 13 (1974).Google Scholar
31. Kimura, J. and Kubota, N., Prop. Explos., 5, 1 (1980).Google Scholar
32. Karpowicz, R. J. and Brill, T. B., Combust. Flame, 56, 317 (1984).Google Scholar
33. Behrens, R., J. Phys. Chem., 94, 6706 (1990).Google Scholar
34. Palopoli, S. F. and Brill, T. B., Combust. Flame, 87, 45 (1991).Google Scholar