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Spectroscopic Investigations of the Network Structure in Borovanadate Glasses

Published online by Cambridge University Press:  10 February 2011

O. Attos ,
M. Massot ,
H. S. Mavi  and
C. Julien
O. Attos
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
M. Massot
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
H. S. Mavi
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
C. Julien
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
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Abstract

Borovanadate glasses with mixed conductivity, i.e., simultaneous ionic and electronic carriers have been obtained in the system (100−x)[B2O3-Li2O]-xV2O5 (0 ≤ x ≤ 30 mole%). To understand the origin of the conductivity in these glasses, the compositional dependence of the network structure has been studied by Raman and infrared spectroscopy.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 455: Symposium T – Glasses and Glass Formers–Current Issues , 1996 , 477
Copyright
Copyright © Materials Research Society 1997

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References

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