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Raman Spectroscopy for Probing guest-host interactions in Metal Organic Frameworks

Published online by Cambridge University Press:  22 August 2011

Nour Nijem ,
Katy Roodenko ,
Yonggang Zhao ,
Jing Li  and
Yves J. Chabal
Nour Nijem
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
Katy Roodenko
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
Yonggang Zhao
Affiliation:
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, U.S.A.
Jing Li
Affiliation:
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, U.S.A.
Yves J. Chabal
Affiliation:
Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, U.S.A.
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Abstract

Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO2, N2 and CH4 with Zn(bdc)(ted)0.5.

Keywords

Raman spectroscopymethaneIr

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References

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