Hostname: page-component-54dcc4c588-54gsr Total loading time: 0 Render date: 2025-10-12T15:41:49.711Z Has data issue: false hasContentIssue false

Radiation Stability of Crown Ether Used for Decontamination ofRadionuclides from HLW

Published online by Cambridge University Press:  03 September 2012

Vyacheslav M. Abashkin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, vs@khimcon.msk.ru
Gennadiy F. Egorov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, vs@khimcon.msk.ru
Evgeniy Filippov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, vs@khimcon.msk.ru
Anna K. Nardova
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, vs@khimcon.msk.ru
Igor V. Mamakin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, vs@khimcon.msk.ru
Get access

Abstract

The gamma-ray initiated oxidation of dicyclohexano-18-crown-6 (DCH-6) wasstudied in two-phase system under agitation: nitric acid, aqueous solutionand organic solvent.

The distribution coefficients of radionuclides, hydrodynamic characteristics(phase separation and interface surface tension), and the radiolysisproducts after irradiation at a dose rate (60Co) of 1.7 Gy/s weredetermined. The maximum total dose was 3.O×105 Gy (3.0×107R).

Information

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Melson, G.A., Coordination Chemistry of Macrocvclic Compounds, Plenum Press, New York and London, 1979.Google Scholar
2. Egorov, G.V., Radiochemistry of Solvent Extraction Systems Energoizdat, Moscow, 1986.Google Scholar
3. Horwitz, E.P., Dietz, M.L., and Fisher, D.E., SREX: A new process for the extraction and recovery of Strontium from acidic nuclear waste streams. Solvent Extr. Ion Exck, 8, 199 (1990).Google Scholar
4. Filippov, Y. A., Dzekun, E.A., Nardov, A.K. et al. (1992) Application of crown ethers and ferrocvanide based inorganic material for cesium and strontium recovery. In Proceedings of the Annual Symposium on Waste Management at Tucson AZ, 2, 1021 (1992).Google Scholar
5. Pyatnitski, I.V. Chemistry and Technology of Water (Rus.). Naukova Dumka: Kiev, 1983, 5, P.224.Google Scholar