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Processing of Inorganic-Organic Hybrids From Metal Alkoxides and Phenyltriethoxysilane

Published online by Cambridge University Press:  10 February 2011

Ikuko Yoshinaga ,
Noriko Yamada ,
Shingo Katayama ,
B. Claflin  and
G. Lucovsky
Ikuko Yoshinaga
Affiliation:
Nippon Steel Corporation, Advanced Technology Research Laboratories, 3-35-1 Ida, Nakahara-ku, Kawasaki 211-0035, JAPAN, ikko@labl.nsc.co.jp
Noriko Yamada
Affiliation:
Nippon Steel Corporation, Advanced Technology Research Laboratories, 3-35-1 Ida, Nakahara-ku, Kawasaki 211-0035, JAPAN, ikko@labl.nsc.co.jp
Shingo Katayama
Affiliation:
Nippon Steel Corporation, Advanced Technology Research Laboratories, 3-35-1 Ida, Nakahara-ku, Kawasaki 211-0035, JAPAN, ikko@labl.nsc.co.jp
B. Claflin
Affiliation:
Nippon Steel Corporation, Advanced Technology Research Laboratories, 3-35-1 Ida, Nakahara-ku, Kawasaki 211-0035, JAPAN, ikko@labl.nsc.co.jp
G. Lucovsky
Affiliation:
Nippon Steel Corporation, Advanced Technology Research Laboratories, 3-35-1 Ida, Nakahara-ku, Kawasaki 211-0035, JAPAN, ikko@labl.nsc.co.jp
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Abstract

In the synthesis of inorganic-organic hybrids from metal alkoxides and phenyltriethoxysilane (PTES), metal alkoxides were found to influence the phenyl siloxane network formation. The presence of metal alkoxides in the initial stage of hydrolysis and condensation of PTES promote the formation of phenyl siloxane networks to provide a dense hybrid. However, the presence of metal alkoxides in the stage of hydrolyzed PTES provide a loose structure of phenyl siloxane networks involving a number of silanol groups.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 285
Copyright
Copyright © Materials Research Society 1998

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