Hostname: page-component-54dcc4c588-hp6zs Total loading time: 0 Render date: 2025-10-06T06:25:00.622Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Amazingly Hard polyHIPE material from a Direct Emulsion

Published online by Cambridge University Press:  01 February 2011

Carlos Youssef ,
Rénal Backov ,
Mona Treguer ,
Marc Birot  and
Hervé Deleuze
Carlos Youssef
Affiliation:
carlos.joseph@hotmail.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
Rénal Backov
Affiliation:
backov@crpp-bordeaux.cnrs.fr, Centre de Recherche Paul Pascal, UPR 8641-CNRS, 115 Avenue Albert Schweitzer, Université de Bordeaux, 33600 Pessac, France
Mona Treguer
Affiliation:
treguer@icmcb-bordeaux.cnrs.fr, Institut de Chimie de la Matière Condensée, UPR 9048-CNRS, 87 Avenue Albert Schweitzer, Université de Bordeaux, 33608 Pessac, France
Marc Birot
Affiliation:
m.birot@ism.u-bordeaux1.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
Hervé Deleuze
Affiliation:
herve.deleuze@u-bordeaux1.fr, Institut des Sciences Moléculaires, UMR-CNRS 5255, 351 cours de la Libération, Université de Bordeaux, 33405 Talence, France
Get access

Abstract

Interconnected microcellular polymeric monoliths having unexpected high mechanical strength have been prepared using the High Internal Phase Emulsion methodology. Direct concentrated emulsions of aqueous 5-amino-1-vinyl-[1,2,3,4]tetrazole mixed with low molar (5 %) fractions of N,N'-methylenebisacrylamide (MBA) as cross-linking agent were prepared using dodecane as dispersed phase and a mixture of hydrophilic surfactants. “Reverse” polyHIPE materials were obtained after radical copolymerization, solvent extraction and drying. Their morphology, chemical composition and physico-chemical behaviour are discussed.

Keywords

polymerizationporosityscanning electron microscopy (SEM)

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1269: Symposium FF – Polymer Materials and Membranes for Energy Devices , 2010 , 1269-FF03-07
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1 Barby, D.; Haq, Z. Eur. Pat. 60, 138, 1982.Google Scholar
2 Lissant, K. J. in Emulsions and Emulsions Technology Part 1, Marcel Dekker Inc., New York, 1974.Google Scholar
3 Taylor, S. P. Rec. Res. Devel. Surf. Col. 2004, 1, 183.Google Scholar
4 Menner, A.; Powell, R.; Bismarck, A. Macromolecules 2006, 39, 2034.Google Scholar
5 Cameron, N. R.; Sherrington, D. C. Adv. Polym. Sci. 1996, 126, 163.Google Scholar
6 Silverstein, M. S.; Tai, H. W.; Sergienko, A.; Lumelsky, Y. L. L.; Pavlovsky, S.; Polymer 2005, 46, 6682.Google Scholar
7 Akay, G.; Birch, M. A.; Bohkhari, M. A. Biomaterials 2004, 25, 3991.Google Scholar
8 Krajnc, P.; Brown, J. F.; Cameron, N. R. Org. Lett. 2002, 4, 2497.Google Scholar
9 Menner, A.; Ikem, V.; Salgueiro, M.; Shaffer, , M. S. P., ; Bismarck, , A. Chem. Commun. 2007, 4274.Google Scholar
10 Lucchesi, C.; Pascual, S.; Dujardin, G.; Fontaine, , L. React. Funct. Polym. 2008, 68, 97.Google Scholar
11 Williams, J. M.; Wrobleski, D. A. Langmuir 1988, 4, 656.Google Scholar
12 Williams, J. M.; Gray, A. J.; Wilkerson, M. H. Langmuir 1990, 6, 437.Google Scholar
13 Akay, G.; Bhumgara, Z.; Wakeman, R. J. Chem. Eng. Res. Dev. 1995, 73, 782.Google Scholar
14 Barbetta, A.; Cameron, N. R.; Cooper, S. J Chem. Commun. 2000, 221.Google Scholar
15 Barbetta, A.; N. R., Cameron Macromolecules 2004, 37, 3188.Google Scholar
16 Barbetta, A.; N. R., Cameron Macromolecules 2004, 37, 3202.Google Scholar
17 Tai, H.; Sergienko, A.; Silverstein, M. S. Polym. Eng. Sci. 2001, 41, 1540.Google Scholar
18 Normatov, J.; Silverstein, M. S. Macromolecules 2007, 40, 8329.Google Scholar
19 Menner, A.; Powell, R.; Bismarck, A. Soft Mat. 2006, 4, 337.Google Scholar
20 Leber, N.; Fay, J. D. B.; Cameron, N. R.; Krajnc, P. J. Polym. Sci. A Polym. Chem. 2007, 45, 4043.Google Scholar
21 Junkar, I.; Koloini, T.; Krajnc, P.; Nemec, D.; Podgornik, A.; Strancar, A. J. Chromatogr. A. 2007, 1144, 48.Google Scholar
22 Krajnc, P.; Stefanec, D.; Pulko, I. Macromol. Rapid Comm. 2005, 26, 1289.Google Scholar
23 Ko, Y. C.; Lindsay, J. D. World Pa Pat. t. 044, 041, 2004.Google Scholar
24 Barbetta, A.; Dentini, M.; Zannoni, E. M.; M., De Stefano Langmuir 2005, 21, 12333.Google Scholar
25 Barbetta, A.; Dentini, M.; De Vecci, M. S.; Filippini, P.; Formisano, G.; Caiazza, S. Adv. Funct. Mat. 2005, 15, 118.Google Scholar
26 Duke, J. R.; Hoisington, M. A.; La Langlois, D. A.; , Benicewicz, nglois, B. C., Polymer 1998, 39, 4369.Google Scholar
27 Cameron, N. R.; Sherrington, D. C. Macromolecules 1997, 30, 5860 Google Scholar
28 Lëpine, O.; Birot, M.; Deleuze, H. Macro. Mat. Eng. 2009, 294, 599 Google Scholar
29 Lëpine, O.; Deleuze, H. Coll. Polym. Sci. 2008, 286, 1273 Google Scholar
30 Audouin, F.; Birot, M.; Pasquinet, E.; Deleuze, H.; Besnard, O.; Poullain, D. J. Appl. Polym. Chem. 2008, 108, 2808 Google Scholar
31 Grosse, M Birot, M-T., Lamotte, M., M., ; Deleuze, H. J. Polym. Sci. A Polym. Chem. 2008, 46, 21 Google Scholar
32 Lëpine, O.; Birot, M.; Deleuze, H. J. Polym. Sci. A Polym. Chem. 2007, 45, 4193 Google Scholar
33 Barmin, M. I.; Gromava, S. A.; Mel'nikov, V. V. Russ. J. Appl. Chem. 2001, 74, 1156.Google Scholar
34 Arnold, C.; Thatcher, D. N. J. Org. Chem. 1969, 34, 1141.Google Scholar
35 Besnard, O.; Pasquinet, E.; Birot, M.; Deleuze, H.; Audouin, F. Fr. Pat. 08 53809, 2008.Google Scholar
36 Menner, A.; Salgueiro, M.; Shaffer, M. S. P.; Bismark, A., J. Polym. Sci., Part A Polym. Chem. 2008, 46, 5708.Google Scholar
37 Ermakova, T. G.; Kuznetsova, N. P.; Tatarova, L. A.; Lopyrev, V. A. Russ. J. Gen. Chem. 2007, 77, 132.Google Scholar