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A New Synthetic Route to Alkyl Terminated Silicon Nanoparticles.

Published online by Cambridge University Press:  11 February 2011

Katherine A. Pettigrew ,
Philip P. Power  and
Susan M. Kauzlarich
Katherine A. Pettigrew
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
Philip P. Power
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
Susan M. Kauzlarich
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
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Abstract

This paper describes the preparation of alkyl terminated silicon nanoparticles that are air and moisture stable by the oxidation of magnesium silicide with bromine and then the subsequent termination with an alkyl Grignard reagent. The nanoparticles have been characterized by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy, and fluorescence spectroscopy.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 737 , 2002 , F1.8
Copyright
Copyright © Materials Research Society 2003

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References

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