Hostname: page-component-54dcc4c588-b5cpw Total loading time: 0 Render date: 2025-10-12T04:19:07.530Z Has data issue: false hasContentIssue false
  • English
  • Français

New Hybrid Inorganic/Organic Block Copolymers as Templates for the Formation of Mesostructured Materials

Published online by Cambridge University Press:  01 February 2011

Guido Kickelbick ,
Josef Bauer  and
Nicola Hüsing
Guido Kickelbick
Affiliation:
Institut für Anorganische Chemie, Technische Universität Wien, Getreidemarkt 9, A-1060 Wien, AUSTRIA
Josef Bauer
Affiliation:
Institut für Anorganische Chemie, Technische Universität Wien, Getreidemarkt 9, A-1060 Wien, AUSTRIA
Nicola Hüsing
Affiliation:
Institut für Anorganische Chemie, Technische Universität Wien, Getreidemarkt 9, A-1060 Wien, AUSTRIA
Get access

Abstract

Amphiphilic block copolymers were prepared with poly(dimethylsiloxane) (PDMS) as the hydrophobic unit. The hydrophilic block was composed of either a poly (ethylene oxide) or a functionalized polysiloxane unit. The polymer based on polysiloxane blocks only, represents one of the first examples of a new class of surfactants with a purely inorganic Si-O backbone. Beside their potential use as templates for the synthesis of mesostructured inorganic materials, these new polymers offer the possibility of being transformed into porous mesostructured silica-based material by controlled pyrolysis.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC3.1
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Raman, N. K., Anderson, M. T., and Brinker, C. J., Chem. Mater., 8, 1682 (1996).Google Scholar
2. Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., and Beck, J. S., Nature, 359, 710 (1992).Google Scholar
3. Soten, I. and Ozin, G. A., Curr. Opin. Coll. Int. Sci., 4, 325 (1999).Google Scholar
4. Zaho, D., Feng, J., Huo, Q., Melosh, N., Fredickson, G. H., Chmelka, B. F., and Stucky, G. D., Science, 279, 548 (1998).Google Scholar
5. Schmidt-Winkel, P., Lukens, W. W., Zaho, D., Yang, P., Chmelka, B. F., and Stucky, G. D., J. Am. Chem. Soc., 121, 254 (1999).Google Scholar
6. Yang, P., Deng, T., Zhao, D., Feng, P., Pine, D., Chmelka, B. F., Whitesides, G. M., and Stucky, G. D., Science, 282, 2244 (1998).Google Scholar
7. Yang, P., Zaho, D., Margolese, D. I., Chmelka, B. F., and Stucky, G. D., Nature, 396, 152 (1998).Google Scholar
8. Yang, P., Zaho, D., Margolese, D. I., Chmelka, B. F., and Stucky, G. D., Chem. Mater., 11, 2813 (1999).Google Scholar
9. Saljoughian, M., Monatsh. Chem., 115, 519 (1984).Google Scholar
10. Miller, P. J. and Matyjaszewski, K., Macromolecules, 32, 8760 (1999).Google Scholar
11. Mazurek, M. and Chojnowski, J., Makromol. Chem., 178, 1005 (1977).Google Scholar
12. Antonietti, M., Förster, S., Hartmann, J., and Oestereich, S., Macromolecules, 29, 3800 (1996).Google Scholar