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Fullerenes as Nanoscale “Connectors”

Published online by Cambridge University Press:  15 February 2011

Mark S. Meier ,
Douglas J. Rice ,
Craig Thomas ,
Vahid Majidi ,
Robert Pogue  and
Magdalena Poplawska
Mark S. Meier
Affiliation:
Department of Chemistry, University of Kentucky, Lexington, KY 40506–0055
Douglas J. Rice
Affiliation:
Department of Chemistry, University of Kentucky, Lexington, KY 40506–0055
Craig Thomas
Affiliation:
Department of Chemistry, University of Kentucky, Lexington, KY 40506–0055
Vahid Majidi
Affiliation:
Department of Chemistry, University of Kentucky, Lexington, KY 40506–0055
Robert Pogue
Affiliation:
Department of Chemistry, University of Kentucky, Lexington, KY 40506–0055
Magdalena Poplawska
Affiliation:
Faculty of Chemistry, Warsaw Technical University (Politechnika), 00–664 Warszawa, Noakowskiego 3, Poland
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Abstract

The construction of nanoscale devices is a potentially important area of technology. Efforts in this area of chemistry have largely concentrated on the preparation of rigid organic molecules for use as spacers. These compounds are used to separate electronically active units, usually metal complexes, by defined distances.

We have been investigating the use of fullerenes as connectors in the construction of these extended assemblies. In this paper we will present our results on the preparation of these compounds, including discussions of the regiochemistry of the second addition of a nitrile oxide to a fullerene isoxazoline.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 359: Symposium G – Science and Technology of Fullerene Materials , 1994 , 369
Copyright
Copyright © Materials Research Society 1995

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References

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