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Formation of Vivianite During Microbiologically Influenced Corrosion of Steels

Published online by Cambridge University Press:  25 February 2011

Michael McNeil  and
Jennifer McKay
Michael McNeil
Affiliation:
Office of Nuclear Regulatory Research, Nuclear Regulatory Commission, Washington DC 20555
Jennifer McKay
Affiliation:
Department of Earth Sciences, University of Western Ontario, London ON N6A 5B7
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Abstract:

Exposure of carbon and HY-80 high strength low alloy (HSLA) steels to anaerobic Postgate cultures containing sulfate reducing bacteria leads to production of mackinawite, Fe9S8, and vivianite, Fe3(PO4)2.8H2O, with minor amounts of other minerals, the vivianite being sometimes accompanied by siderite, FeCO3. The vivianite and mackinawite persist on exposure to air or oxygenated water. Green rust is a significant alteration product on some steels. The implications of these findings are discussed in light of present and possible future nuclear waste containers.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 333: Symposium V – Scientific Basis for Nuclear Waste Management XVII , 1993 , 699
Copyright
Copyright © Materials Research Society 1994

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References

References:

1 Booth, G. H. and Wormwell, F., in Proceedings of the First International Congress on Metallic Corrosion (Butterworths, London, 1962).Google Scholar
2 Biologically Induced Corrosion, ed. Dexter, S. C. (National Association of Corrosion Engineers, Houston, TX, 1986).Google Scholar
3 Iverson, W. P., Advances in Applied Microbiology 32, 1 (1986).Google Scholar
4 Weimer, P. J., van Kavelaar, M. J., Michel, C. B., and Ng, T. K., Applied and Environmental Microbiology 54, 386–396 (1988).CrossRefGoogle Scholar
5 McNeil, M. B. and Little, B. J., Corrosion 46, 599–601 (1990).Google Scholar
6 Hamilton, W. A., in Biofouling and Biocorrosion in Industrial Water Systems (Springer Verlag, Berlin, 1990).Google Scholar
7 McNeil, M. B. and Odom, A. L., Prediction of Microbiologically Influenced Corrosion of Alloys: Corrosion Influenced by Sulfate Reducing Bacteria , in Microbiologically Influenced Corrosion Testing (ASTM, Philadelphia, PA 1993, in press).Google Scholar
8 Hackett, E. M., Link, L. R., and Blackburn, J. M., Metallurgical, Mechanical Property, and Weldability Evaluations of Commercial..Steels, Report DTRC/SME-89-56 (David Taylor Research Center, 1989).Google Scholar
9 Bryant, R. D. and Laishley, E. J., Canadian J. of Microbiology 36, 259–264 (1990).CrossRefGoogle Scholar
10 Bryant, R. D. and Laishley, E. J., Applied Microbiology and Biotechnology 38, 824–827 (1993).Google Scholar
11 Jack, T., private communication (1993).Google Scholar
12 Postma, D., American Journal of Science 282, 1151 (1982).CrossRefGoogle Scholar
13 Garrels, R. M. and Christ, C. L., Solutions, Minerals, and Eguil ibria, (Harper and Row, New York, 1965).Google Scholar
14 Jakobsen, B. H., Journal of Soil Science 39, 447 (1988).CrossRefGoogle Scholar
16 McNeil, M. B. and Little, B. J., Corrosion 46, 599 (1990).Google Scholar
17 Jorgensen, B., Isaksen, M. F., and Jannasch, H. W., Science 258,1756 (1992).Google Scholar