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The design of Optical Limiters Based on the Formation of Bipolaron-Like Dications

Published online by Cambridge University Press:  03 September 2012

Charles W. Spangler  and
Mingqian He
Charles W. Spangler
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 95717, uchcs@earth.oscs.montana.edu
Mingqian He
Affiliation:
Department of Chemistry, University of Southern California, Los Angeles, California 90089
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Abstract

During the past decade, there has been considerable effort in the design of new materials with greatly enhanced nonlinear absorption characteristics. In recent years, it has been shown that incorporation of bipolaronic charges in the pi-electron sequence in conjugated polymers or copolymers leads to enhanced third-order nonlinear optical properties. In this current study a design strategy for the synthesis of optical power limiting copolymers is presented whose properties are based on the photogeneration of stable bipolaron-like dications.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 479: Symposium S – Materials for Optical Limiting II , 1997 , 59
Copyright
Copyright © Materials Research Society 1997

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