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Quantitative evaluation of bundling effect on single walled carbon nanotubes by resonance Raman spectra

Published online by Cambridge University Press:  01 February 2011

Zhengtang Luo ,
Rongfu Li ,
Sang Nyon Kim  and
Fotios Papadimitrakopoulos
Zhengtang Luo
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Rongfu Li
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Sang Nyon Kim
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Fotios Papadimitrakopoulos*
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
*
email: papadim@mail.ims.uconn.edu
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Abstract

The radial breathing mode (RBM) region of the resonance Raman spectra of HiPco single walled carbon nanotubes (SWNTs) was investigated as a function of aggregation. This was modeled using an energetic deviation term (ΔE), imparted to the optical transitions (E ii (n, m)) by bundling effect. E ii (n, m) values obtained from photoluminescence (PL) measurements were used to reconstruct these RBM profiles. The simulation revealed that the PL-determined E ii (n, m) set provided a good fit in terms of peak position. Providing an accurate set of E ii (n, m) values becomes available, the RBM profile reconstruction methodology discussed herein could greatly enhance our ability to model a range of physicochemical changes to the immediate environment of SWNTs.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 858: Symposium HH – Functional Carbon Nanotubes , 2004 , HH13.14
Copyright
Copyright © Materials Research Society 2005

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References

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