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Metal Nanoparticles/BDD Hybrid Electrodes for Analytical Detection ofPollutants in Water

Published online by Cambridge University Press:  29 February 2016

Dounia K. Belghiti ,
Emmanuel Scorsone  and
Philippe Bergonzo
Dounia K. Belghiti*
Affiliation:
CEA, LIST, Diamond Sensors Laboratory, 91191, Gif-sur-Yvette, France
Emmanuel Scorsone
Affiliation:
CEA, LIST, Diamond Sensors Laboratory, 91191, Gif-sur-Yvette, France
Philippe Bergonzo
Affiliation:
CEA, LIST, Diamond Sensors Laboratory, 91191, Gif-sur-Yvette, France
*
*(Email: Dounia.belghiti@CEA.fr)
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Abstract:

Boron Doped Diamond (BDD) electrodes exhibit excellent properties including awide potential window in aqueous media, high corrosion resistance, chemicalinertness, bio-compatibility and low background current. In order to increasetheir selectivity for analytical applications, several studies were carried outrecently on the possibility to deposit metal nanoparticles such as Pt or Ir onsuch BDD electrodes1,2,3,4. Indeed these nanoparticles bringinteresting electro-catalytic properties to the electrodes, thus offering thepossibility to address new analytes. Here an electrode array was developed,based on multiple BDD electrodes casted with various metal nanoparticles. Thesimultaneous detection of analytes by each electrode composing the array givespotentially a unique fingerprint to the analytes, thus increasing thespecificity and the selectivity of the sensor.

Keywords

diamondnanoscalesensor

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Type
Articles
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MRS Advances , Volume 1 , Issue 16: Electronics and Photonics , 2016 , pp. 1131 - 1136
Copyright
Copyright © Materials Research Society 2016 

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References

Elzanowska, H., Abu-Irhayem, E., Skrzynecka, B. & Birss, V. I. Hydrogen Peroxide Detection at Electrochemically and Sol-Gel Derived Ir Oxide Films. Electroanalysis 16, 478–490 (2004).Google Scholar
He, Z., Chen, J., Liu, D., Zhou, H. & Kuang, Y. Electrodeposition of Pt–Ru nanoparticles on carbon nanotubes and their electrocatalytic properties for methanol electrooxidation. Diam. Relat. Mater. 13, 1764–1770 (2004).Google Scholar
Limat, M., Roustom, B. El, Jotterand, H., Fóti, G. & Comninellis, C. Electrochemical and morphological characterization of gold nanoparticles deposited on boron-doped diamond electrode. Electrochim. Acta 54, 2410–2416 (2009).Google Scholar
Salimi, A., Hyde, M. E., Banks, C. E. & Compton, R. G. Boron doped diamond electrode modified with iridium oxide for amperometic detection of ultra trace amounts of arsenic(iii). Analyst 129, 9–14 (2004).Google Scholar
Holmin, S., Björefors, F., Eriksson, M., Krantz-Rülcker, C. & Winquist, F. Investigation of electrode materials as sensors in a voltammetric electronic tongue. Electroanalysis 14, 839–847 (2002).Google Scholar
Winquist, F., Holmin, S., Krantz-Rülcker, C., Wide, P. & Lundström, I. A hybrid electronic tongue. Anal. Chim. Acta 406, 147–157 (2000).CrossRefGoogle Scholar
Siné, G., Fóti, G. & Comninellis, C. Boron-doped diamond (BDD)-supported Pt/Sn nanoparticles synthesized in microemulsion systems as electrocatalysts of ethanol oxidation. J. Electroanal. Chem. 595, 115–124 (2006).CrossRefGoogle Scholar
Welch, C.M.Banks, C.E.Compton, R. G. Silver nanoparticle assemblies supported on glassy-carbon electrodes for the electro-analytical detection of hydrogen peroxide. Anal. Bioanal. Chem. 382, 12–21 (2005).Google Scholar
Wipf, D. O., Ge, F., Spaine, T. W. & Baur, J. E. Microscopic Measurement of pH with Iridium Oxide Microelectrodes. Anal. Chem. 72, 4921–4927 (2000).Google Scholar
Wang, Q. & Zheng, J. Electrodeposition of silver nanoparticles on a zinc oxide film: improvement of amperometric sensing sensitivity and stability for hydrogen peroxide determination. Microchim. Acta 169, 361–365 (2010).Google Scholar
Terashima, C., Rao, T. N., Sarada, B. V, Spataru, N. & Fujishima, A. Electrodeposition of hydrous iridium oxide on conductive diamond electrodes for catalytic sensor applications. J. Electroanal. Chem. 544, 65–74 (2003).Google Scholar
Kiran, R., Scorsone, E., Mailley, P. & Bergonzo, P. Quasi-Real Time Quantification of Uric Acid in Urine Using Boron Doped Diamond Microelectrode with in Situ Cleaning. Anal. Chem. 84, 10207–10213 (2012).CrossRefGoogle ScholarPubMed
Fennouh, S., Casimiri, V. & Burstein, C. Increased paraoxon detection with solvents using acetylcholinesterase inactivation measured with a choline oxidase biosensor. Biosens. Bioelectron. 12, 97–104 (1997).Google Scholar
Xiao, F., Zhao, F., Zhang, Y., Guo, G. & Zeng, B. Ultrasonic Electrodeposition of Gold-Platinum Alloy Nanoparticles on Ionic Liquid-Chitosan Composite Film and Their Application in Fabricating Nonenzyme Hydrogen Peroxide Sensors. J. Phys. Chem. C 113, 849–855 (2009).Google Scholar