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Gas Chromatographic Pathways for Certain Chloro-Alkylammonium Montmorillonites

Published online by Cambridge University Press:  01 July 2024

James L. McAtee Jr.  and
Brent R. Harris
James L. McAtee Jr.
Affiliation:
Baylor University, Waco, TX 76703, U.S.A.
Brent R. Harris
Affiliation:
Baylor University, Waco, TX 76703, U.S.A.
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Abstract

A series of chloro-alkylammonium montmorillonites was produced by cation exchange from Na+-montmorillonite. Gas chromatographic data were obtained for light hydrocarbons and certain oxides of nitrogen. Surface area and X-ray powder diffraction studies were made on each organo-clay, making possible differentiation between possible chromatographic pathways. Adsorption of the gas molecules on the silicate sheet was determined to be the dominant chromatographic pathway for all gases studied.

Information

Type
Research Article
Information
Clays and Clay Minerals , Volume 25 , Issue 2 , April 1977 , pp. 90 - 93
Copyright
Copyright © Clay Minerals Society 1977

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References

Barrer, R. M. and Hampton, M. G. (1957) Gas chromatography and mixture isotherms in alkylammonium bentonites: Trans. Faraday Soc. 53, 1462–1475.CrossRefGoogle Scholar
Carringer, R. D., Weber, J. B. and Monaco, T. J. (1975) Adsorption–desorption of selected pesticides by organic matter and montmorillonite: J. Agr. Food Chem. 23, 568–572.CrossRefGoogle ScholarPubMed
Chitour, S. E. and Vergnaud, J. M. (1974) A gas–liquid chromatographic study of the adsorption properties of a stationary phase containing a mixture of squaline and Bentone 34: J. Chromatog. 89, 295–307.CrossRefGoogle Scholar
Cowan, C. T. and Hartwell, J. M. (1962) Organo-clay complex for the separation of isomeric dichlorobenzenes using gas chromatography: Nature 190, 712.CrossRefGoogle Scholar
Cowan, C. T. and White, D. (1962) Adsorption by organoclay complexes: Clays & Clay Minerals, pp. 459–467: Pergamon Press, Oxford.CrossRefGoogle Scholar
Datar, A. G., Ramanathan, P. S. and Das, M.S. (1975) Gas–solid chromatographic studies using beryl as adsorbent: J. Chromatog. 106, 428–434.CrossRefGoogle Scholar
Fuchs, D. (1972) Organic derivatives of Hungarian bentonites in hydrocarbon analysis: J. Chromatog. 65, 219–225.CrossRefGoogle Scholar
Kiselve, A. U., Lebedeva, N. P., Frolov, I. I. and Yashim, Y. I. (1972) Liquid-solid chromatography on Bentone 34: Chromatographia 5, 341–345.CrossRefGoogle Scholar
Legate, C. E. and Johns, W. D. (1964) Gas-chromatographic examination of several systems from clay minerals and organic materials: Beitr. Mineral Petrographie 10, 60–69.Google Scholar
Manara, G. and Taramasso, M. (1972) Sieving effects of hormites in gas-adsorption chromatography: J. Chromatog. 65, 349–353.CrossRefGoogle Scholar
Mortimer, J. V. and Gent, P. L. (1963) Modified Bentone 34 for the gas-chromatographic separation of aromatic hydrocarbons: Nature 197, 189.CrossRefGoogle Scholar
Mortimer, J. V. and Gent, P. L. (1964) The use of organoclays as gas chromatographic stationary phases: Anal. Chem. 36, 754–756.CrossRefGoogle Scholar
Taramasso, M. and Fuchs, P. (1970) The organic complexes of the clay minerals and their use in gas chromatography: J. Chromatog. 49, 70–75.CrossRefGoogle Scholar
Thielman, Vernon J. and McAtee, James L. Jr. (1975) Gas chromatographic behavior of metal-tris (ethylenediamine) complex cation-exchanged montmorillonite: J. Chromatog. 105, 115–123.CrossRefGoogle Scholar
Thomas, J. and Bohar, B. F. (1968) Surface area of montmorillonite from the dynamic sorption of nitrogen and carbon dioxide: Clays & Clay Minerals 16, 83–92.CrossRefGoogle Scholar
Van Rysselberge, J. and Vander Stricht, M. (1962) Complex separation of xylenes and ethyl benzene by gas chromatography: Nature 193, 1281–1282.CrossRefGoogle Scholar
White, D. (1957) Use of orgamc-montmorillonite compounds in gas chromatography: Nature 179, 1075–1076.CrossRefGoogle Scholar