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Characterization of Iron-Rich Phyllosilicates Formed at Different Fe/Si Ratios

Published online by Cambridge University Press:  01 January 2024

Liva Dzene Open the ORCID record for Liva Dzene [Opens in a new window] ,
Patrick Dutournie ,
Jocelyne Brendle ,
Lionel Limousy ,
Jean-Marc Le Meins ,
Laure Michelin ,
Loïc Vidal ,
Simon Gree ,
Mustapha Abdelmoula  and
Christelle Martin
...Show all authors
Liva Dzene*
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Patrick Dutournie
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Jocelyne Brendle
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Lionel Limousy
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Jean-Marc Le Meins
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Laure Michelin
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Loïc Vidal
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Simon Gree
Affiliation:
Institut de Science des Matériaux de Mulhouse CNRS UMR 7361, Université de Haute-Alsace, Université de Strasbourg, 3b rue Alfred Werner, 68093, Mulhouse CEDEX, France
Mustapha Abdelmoula
Affiliation:
LCPME, CNRS-Université de Lorraine UMR7564, F-54000, Nancy, France
Christelle Martin
Affiliation:
Andra, R&D Division, Packages and Materials Department, 1/7 rue Jean Monnet, F-92298, Châtenay-Malabry CEDEX, France
Nicolas Michau
Affiliation:
Andra, R&D Division, Packages and Materials Department, 1/7 rue Jean Monnet, F-92298, Châtenay-Malabry CEDEX, France
*
e-mail: liva.dzene@uha.fr
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Abstract

The formation of 2:1 and 1:1 phyllosilicates in Fe–Si–O–H systems occurs in various geological and engineering settings; however, the identification and characterization of these minerals is very challenging due to the limited amount that is accessible, the very small particle size, and often the large degree of heterogeneity of these samples. To overcome these drawbacks, the synthesis of iron-rich phyllosilicates was attempted in this study with an initial Fe/Si molar ratio ranging from 0.50 to 2.33. The synthesis was performed at 150°C under hydrothermal conditions over a period of 7 days. Synthesis products were characterized by X-ray diffraction and fluorescence, by infrared, Raman, and Mössbauer spectroscopies, and by transmission electron microscopy. Results revealed that the stability field of the 2:1 clay mineral was wider than that of the 1:1 clay mineral. The 2:1 clay mineral was less sensitive to redox conditions compared to the 1:1 clay mineral. In addition, a heterogeneity of phases formed (iron oxides, nontronite, cronstedtite, or greenalite) was identified.

Keywords

BerthierineCronstedtiteGreenaliteNontroniteSerpentineSynthesis

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Type
Original Paper
Information
Clays and Clay Minerals , Volume 70 , Issue 4 , August 2022 , pp. 580 - 594
Copyright
Copyright © The Author(s), under exclusive licence to The Clay Minerals Society 2022

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Footnotes

Associate Editor: Jinwook Kim

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